Product ID:264569, TERMIDOR 80 WG INSECTICIDE
MSDS Date:02/21/2001
FSC:6840
NIIN:01-483-3072
Status Code:A
MSDS Number: CLLYX

Emergency Phone: (800) 424-9300

Info Phone: (800) 331-2867

Preparer: DEPT OF REGULATORY AFFAIR

Cage: UO368

Telephone: (800) 331-2867

Cage: UO368

FIPRONIL

CAS: 120068-37-3

INERT INGREDIENTS

Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:SKIN: MAY BE FATAL IF ABSORBED THROUGH
SKIN. MAY PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. EYES:
CAUSES SUBSTANTIAL BUT TEMPORARY EYE INJURY. MAY CAUSE REDNESS,
IRRITATION AND TEARING. INHALAT ION: MAY BE FATAL IF INHALED. MAY
PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. MAY CAUSE
SHORTNESS OF BREATH, EXCITEMENT, INVOLUNTARY SHAKING, CONVULSIONS,
IRRITABILITY. INGESTION: MAY BE FATAL I F SWALLOWED. MAY CAUSE
SHORTNESS OF BREATH, INVOLUNTARY SHAKING, CONVULSIONS, EXCITEMENT.
Explanation of Carcinogenicity:THIS PRODUCT DOES NOT CONTAIN ANY
INGREDIENT DESIGNATED BY THE IARC, NTP, ACGIH, OR OSHA AS PROBABLE
OR SUSPECTED HUMAN CARCINOGENS.
Effects of Overexposure:SKIN: MAY BE FATAL IF ABSORBED THROUGH SKIN.
MAY PRODUCE SYMPTOMS SIMILAR TO THOSE FROM INGESTION. EYES: CAUSES
SUBSTANTIAL BUT TEMPORARY EYE INJURY. MAY CAUSE REDNESS, IRRITATION
AND TEARING. INHALAT ION: MAY BE FATAL IF INHALED. MAY PRODUCE
SYMPTOMS SIMILAR TO THOSE FROM INGESTION. MAY CAUSE SHORTNESS OF
BREATH, EXCITEMENT, INVOLUNTARY SHAKING, CONVULSIONS, IRRITABILITY.
INGESTION: MAY BE FATAL I F SWALLOWED. MAY CAUSE SHORTNESS OF
BREATH, INVOLUNTARY SHAKING, CONVULSIONS, EXCITEMENT.
Medical Cond Aggravated by Exposure:INHALATION OF PRODUCT MAY AGGRAVATE
EXISTING CHRONIC RESPIRATORY PROBLEMS SUCH AS ASTHMA, EMPHYSEMA, OR
BRONCHITIS. SKIN CONTACT MAY AGGRAVATE EXISTING SKIN DISEASE.

First Aid:SKIN: WASH WITH PLENTY OF SOAP AND WATER. GET MEDICAL
ATTENTION. REMOVE CONTAMINATED CLOTHING AND SHOES. CLEAN
CONTAMINATED CLOTHING AND SHOES BEFORE REUSE. EYE: FLUSH WITH
PLENTY OF WATER. CALL A PHY SICIAN IF IRRITATION PERSISTS.
INHALATION: REMOVE VICTIM TO FRESH AIR. IF NOT BREATHING, GIVE
ARTIFICIAL RESPIRATION, PREFERABLY MOUTH-TO-MOUTH. GET MEDICAL
ATTENTION. INGESTION: GIVE 1 OR 2 GLASSES O F WATER, AND INDUCE
VOMITING BY TOUCHING BACK OF THROAT WITH FINGER. DO NOT INDUCE
VOMITING OR GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. CALL
A PHYSICIAN OR POISON CONTROL CENTER. DO NOT LEAVE VICTIM
UNATTENDED. (SEE OTHER INFO)

Autoignition Temp:>140.C, 284.F
Extinguishing Media:DRY CHEMICAL, FOAM, WATER, CARBON DIOXIDE.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR NIOSH/MSHA APPROVED
SELF-CONTAINED BREATHING APPARATUS AND FULL PROTECTIVE CLOTHING.
KEEP UNNECESSARY PEOPLE AWAY, ISOLATE HAZARD AREA AND DENY ENTRY.
EVACUATE RESIDENTS WHO A RE DOWNWIND OF FIRE. DIKE AREA TO PREVENT
RUNOFF AND CONTAMINATION OF WATER SOURCES.
Unusual Fire/Explosion Hazard:UNDER FIRE CONDITIONS THE PRODUCT WILL
BURN AND TOXIC, CORROSIVE FUMES EMITTED. HAZARDOUS DECOMPOSITION
MATERIALS (UNDER FIRE CONDITIONS): HYDROGEN FLUORIDE, OXIDES OF
NITROGEN, OXIDES OF SULFUR, OXID ES OF CARBON, HYDROCHLORIC ACID.

Spill Release Procedures:WEAR APPROPRIATE PROTECTIVE GEAR. CLEAN UP
DUST SPILLAGE RESULTING FROM CONTAINER OR PAK BREAKAGE BY SWEEPING
MATERIAL INTO A PILE & AVOID DUST GENERATION. ENSURE ADEQUATE
DECONTAMINATION OF TOOLS & E QUIPMENT FOLLOWING CLEANUP. IF SPILLED
ON THE GROUND, THE AFFECTED AREA SHOULD BE SCRAPED CLEAN & PLACED
IN AN APPROPRIATE CONTAINER FOR DISPOSAL.

Handling and Storage Precautions:DO NOT GET ON SKIN OR IN EYES, OR ON
CLOTHING. DO NOT BREATHE DUST. DO NOT INGEST. MINIMUM / MAXIMUM
STORAGE TEMPERATURES NOT AVAILABLE. DO NOT CONTAMINATE WATER, FOOD,
OR FEED BY STORAGE OR DISPOSAL. STORE IN AN AREA THAT IS AWAY FROM
FOODSTUFFS OR ANIMAL FEED.
Other Precautions:STORE UNUSED PRODUCT IN ORGINAL CONTAINER ONLY, OUT
OF REACH OF CHILDREN AND ANIMALS.

Respiratory Protection:ALL PESTICIDE HANDLERS MUST WEAR A DUST/MIST
FILTERING RESPIRATOR (MSHA/NIOSH APPROVAL NUMBER PREFIX TC-21C), OR
A NIOSH APPROVED RESPIRATOR WITH ANY N, R, P, OR HE FILTER WHEN
WORKING IN A NON-VENTIL ATED SPACE, INCLUDING BUT NOT LIMITED TO
CRAWL-SPACES AND BASEMENTS.
Ventilation:LOCAL EXHAUST VENTILATION AT THE POINT OF GENERATION.
Protective Gloves:CHEMICAL-RESISTANT GLOVES.
Eye Protection:ALL PESTICIDE HANDLERS MUST WEAR PROTECTIVE EYEWEAR.
Other Protective Equipment:ALL PESTICIDE HANDLERS (MIXERS, LOADERS, AND
APPLICATORS) MUST WEAR A LONG -SLEEVED SHIRT AND LONG PANTS, SOCKS,
SHOES, AND CHEMICAL-RESISTANT GLOVES.
Work Hygienic Practices:DO NOT STORE, USE, AND/OR CONSUME FOODS,
BEVERAGES, TOBACCO PRODUCTS, OR COSMETICS IN AREAS WHERE THIS
MATERIAL IS STORED. WASH HANDS AND FACE THOROUGHLY WITH SOAP AND
WATER.
Supplemental Safety and Health
THESE RECOMMENDATIONS PROVIDE GENERAL GUIDANCE FOR HANDLING THIS
PRODUCT. BECAUSE SPECIFIC WORK ENVIRONMENTS AND MATERIAL HANDLING
PRACTICES VARY, SAFETY PROCEDURES SHOULD BE DEVELOPED FOR EACH
INTEND ED APPLICATION. WHILE DEVELOPING SAFE HANDLING PROCEDURES,
DO NOT OVERLOOK THE NEED TO CLEAN EQUIPMENT.

HCC:T4
Boiling Pt:B.P. Text:NOT AVAILABLE
Melt/Freeze Pt:=200.C, 392.F
Vapor Pres:NOT AVAILABLE
Spec Gravity:NOT AVAILABLE
pH:5.63@ 1 WT/WT%
Solubility in Water:DISPERSIBLE
Appearance and Odor:BROWN POWDER; SLIGHT ODOR.

Stability Indicator/Materials to Avoid:YES
STRONG BASES, STRONG ACIDS, STRONG OXIDIZING AGENTS.
Stability Condition to Avoid:DIRECT SUNLIGHT, EXTREME HEAT.
Hazardous Decomposition Products:DECOMPOSITION TEMPERATURE RANGE: 240C
(464F). DECOMPOSITION TYPE: THERMAL- HYDROGEN FLUORIDE, OXIDES OF
NITROGEN, OXIDES OF SULFUR, OXIDES OF CARBON, HYDROCHLORIC ACID.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:WATER SOLUBLE PACKAGES SHOULD BE PLACED DIRECTLY
INTO SPRAY TANKS CONTAINING SOME WATER. THEN DISPOSE OF EMPTY
OVERPACKAGING BAG IN SANITARY LANDFILL OR, IF ALLOWED BY GOVERNMENT
REGULATIONS, BY BURNI NG OR INCINERATION. IF BAG IS BURNED, STAY
OUT OF SMOKE. (SEE OTHER INFORMATION)

Toxicological Information:EYE IRRITATION, RABBIT. MODERATELY
IRRITATING. SKIN IRRITATION, RABBIT. MINIMALLY IRRITATING. SKIN
SENSITIZATION, 0.4 NAP, GUINEA PIG. NOT SENSITIZING. ACUTE DERMAL
TOXICITY: LD50 - LETHAL DOSE 50% OF TEST SPECIES, 374 MG/KG,
RABBIT. ACUTE INHALATION TOXICITY: LC50 - LETHAL CONCENTRATION 50%
OF TEST SPECIES, 0.63 MG/1/4, RAT. NOSE EXPOSURE ONLY. ACUTE ORAL
TOXICITY: LD50 - LETHAL DOSE 50% OF T EST SPECIES, 296 MG/KG, RAT.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:THIS PESTICIDE IS TOXIC TO BIRDS, FISH, & AQUATIC
INVERTEBRATES. DO NOT APPLY DIRECTLY TO WATER OR TO AREAS WHERE
SURFACE WATER IS PRESENT OR TO INTERTIDAL AREAS BELOW THE MEAN HIGH
WATER MARK. RUNOFF FROM TREATED AREAS MAY BE HAZARDOUS TO AQUATIC
ORGANISMS IN NEIGHBORING AREAS. CARE MUST BE TAKEN TO AVOID RUNOFF.
DO NOT CONTAMINATE WATER BY CLEANING EQUIPMENT OR DISPOSAL OF
WASTES. DO NOT CONTAMI NATE WATER WHEN DISPOSING OF EQUIPMENT
WASHWATERS.

Transport Information:PROPER SHIPING NAME: PESTICIDES, SOLID, TOXIC,
NOS (FIPRONIL), 6.1, UN2588, PG III.

SARA Title III Information:SARA TITLE III HAZARD CLASSES: ACUTE HEALTH
HAZARD AND CHRONIC HEALTH HAZARD. SARA 313: NO COMPONENTS LISTED.
State Regulatory Information:THIS PRODUCT DOES NOT CONTAIN ANY
COMPONENTS THAT ARE REGULATED UNDER CALIFORNIA PROPOSITION 65.